A frequent bug for beginners is to assume that 'is' is somehow 'better' then '==' when comparing values, and it is certainly a cause for confusion amongst beginners as to why:

   [1,2] is [1,2] evaluates to False but
   'a' is 'a' evaluates to True

    and many similar examples.

As far as I can see the first mention of the 'is' operator is under Section 5 - More on conditionals : https://docs.python.org/3/tutorial/datastructures.html?highlight=comparison#comparing-sequences-and-other-types; and it is mentioned thus : 

  The operators is and is not compare whether two objects are really
  the same object; this only matters for mutable objects like lists.

As we know though this statement is misleading - it suggests that 'is' can be used to compare immutable values (ints, strings, tuples) etc, and while for some values of some immutables (small ints, shortish strings) 'is' can be used as an equivalent of '==' it wont be clear from this 'statement' that 'is' is simply not a safe way to compare values.

There needs to be a warning here about 'is' and how it is not an equivalent to '==' in any general sense.

I'll add a note to this effect in the tutorial.

Also, in the FAQ, we could have an entry about the three circumstances when "is" can relied upon:  1) variable assignment doesn't change identity, 2) containers that use references don't change identity, and 3) singletons don't change identity.

New changeset f8775e4f72240faba3947eea8efdd83ee56ae1fd by Raymond Hettinger in branch 'master':
bpo-43325: Add FAQ entry for identity tests (GH-25168)
https://github.com/python/cpython/commit/f8775e4f72240faba3947eea8efdd83ee56ae1fd

New changeset de0b2b133011953b02536cc78f2499d5d55224f8 by Miss Islington (bot) in branch '3.9':
bpo-43325: Add FAQ entry for identity tests (GH-25168) (GH-25178)
https://github.com/python/cpython/commit/de0b2b133011953b02536cc78f2499d5d55224f8

Should the data structures page also link to the FAQ. The problem with the FAQ is that most beginners don't even know that == vs 'is' is actually a question they need to ask, and therefore they aren't likely to look at the FAQ in the first place.